yes
no need to sign in on start up.
That's why, because the Keyring doesn't load, if you want to auto-login in Proton VPN you have to not auto-login on Zorin, it's for security, nothing else.
read this if you want to understand how it work
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For Auto connect, put only NL (without #NNN), the VPN will choose the fastest server at the time of connection.
Here is not about auto connect VPN but about auto login in Proton VPN app
I know the title is not clear... I Changed it