Need help with GIMP 2.10.20 flatpak install error

Cliffe, welcome to the Zorin Forum.

If you could, please first run

sudo apt clean

and

sudo apt autoremove

and declutter some crowded hard drive space.

Next, to expand a partition, open Gparted on your system.
You can use the Partition ... resize/ move function to resize or expand a partition. It looks like you have plenty of freespace available that you can expand into.
Usually your Root can be around 50 gigs or so and I personally let my Home folder hog the rest, although I admit I rarely let my home folder grow enough to occupy more than twenty gigs.

For a detailed walkthrough with images, please see the Gparted help guide:
https://gparted.org/display-doc.php%3Fname%3Dmoving-space-between-partitions