WiFi network with two WiFi adapters but only one has a cog

Have you tried removing before, then inserting the USB wifi adpater after ZorinOS is running?

From websearch of "TP-Link AC600 ubuntu 22.04". Maybe something here will help you.

Have you solved this, as I see you have another thread here. Selecting from two WiFi connections . To avoid confusing us, can you please keep to one thread or mark the old one as "Solved" if true.