Libre Office Toolbar Icon Size Too Small... Can't change?

First, elevate the file manager to Root and launch:

nautilus //:admin

Navigate to /usr/share/applications
So in the file manager, you will see usr, double click it. Then share and last, a folder named applications.

In that folder, right click on the .desktop file for libreoffice-writer.desktop
On the exec line, change it to

Exec=env SAL_FORCEDPI=150 libreoffice --writer %U

Save the file.

Test launching writer and make sure Icons are good - if so, you can close the file and the elevated nautilus File Manager.